{"id":3075,"date":"2023-10-04T10:46:12","date_gmt":"2023-10-04T10:46:12","guid":{"rendered":"http:\/\/localhost\/ecole9ja\/?p=3075"},"modified":"2023-10-04T10:48:29","modified_gmt":"2023-10-04T10:48:29","slug":"week-6-ss2-second-term-chemistry-notes","status":"publish","type":"post","link":"https:\/\/ecolebooks.com\/nigeria\/posts\/week-6-ss2-second-term-chemistry-notes\/","title":{"rendered":"Week 6 &#8211; SS2 Second Term Chemistry Notes"},"content":{"rendered":"<p>\u00a0<strong>WEEK SIX\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0DATE: <\/strong>_________<br \/>\n<strong>TOPIC:NITROGEN<br \/>\n<\/strong><strong>CONTENT<br \/>\n<\/strong><\/p>\n<ul>\n<li>General Properties of Nitrogen Family.\n<\/li>\n<li>Laboratory Preparation and Industrial Preparation of Nitrogen.\n<\/li>\n<li>Properties and Uses of Nitrogen.\n<\/li>\n<li>Nitrogen Cycle.\n<\/li>\n<\/ul>\n<p><strong>GENERAL PROPERTIES OF NITROGEN FAMILY (GROUP VA ELEMENTS)<br \/>\n<\/strong>The group V elements include: Nitrogen, Phosphorus, Arsenic, Antimony and Bismuth. There are more differences than similarities between the elements in this group.<\/p>\n<ol>\n<li>\n<div>Nitrogen is a diatomic gas and does not exhibit allotropy. Phosphorus is a typical non-metal and exhibits allotropy. Arsenic and Antimony are metalloid; while bismuth is a metal.\n<\/div>\n<\/li>\n<li>\n<div>Nitrogen is a colourless gas. Phosphorus exists in variety of allotropic forms like white and red phosphorus. Arsenic exists as a dull grey metallic solid. Antimony and bismuth is silvery-white solid.\n<\/div>\n<\/li>\n<li>\n<div>Nitrogen is the most electronegative element in the group. It combines with metals and non-metals to form a variety of compounds.\n<\/div>\n<p>\u00a0<\/li>\n<\/ol>\n<p><strong>ELECTRONIC CONFIGURATION<br \/>\n<\/strong>The electronic configuration of the group V elements is as follows:<br \/>\nNitrogen = 7: 1s<sup>2<\/sup> 2s<sup>2<\/sup> 2p<sup>3<\/sup><br \/>\n\tPhosphorus = 15: 1s<sup>2<\/sup> 2s<sup>2<\/sup> 2p<sup>6<\/sup> 3s<sup>2<\/sup> 3p<sup>3<\/sup><br \/>\n\tArsenic = 33: 1s<sup>2<\/sup> 2s<sup>2<\/sup> 2p<sup>6<\/sup> 3s<sup>2<\/sup> 3p<sup>6<\/sup> 3d<sup>10<\/sup> 4s<sup>2<\/sup> 4p<sup>3<\/sup><br \/>\n\tAntimony   = 51: 1s<sup>2<\/sup> 2s<sup>2<\/sup> 2p<sup>6<\/sup> 3s<sup>2<\/sup> 3p<sup>6<\/sup> 3d<sup>10<\/sup> 4s<sup>2<\/sup> 4p<sup>6 <\/sup>4d<sup>10<\/sup> 5s<sup>2<\/sup> 5p<sup>3<br \/>\n<\/sup><br \/>\n\u00a0<strong>NITROGEN<br \/>\n<\/strong>Nitrogen occurs chiefly as a free element in the air. It makes up 78% by volume of the atmosphere. It also exists in combined form in many compounds e.g ammonia, urea, proteins etc. <\/p>\n<p>\u00a0<strong>LABORATORY PREPARATION<br \/>\n<\/strong><strong>From Air<br \/>\n<\/strong>It can be obtained from air by passing air through caustic soda to remove CO<sub>2<\/sub> and<br \/>\noverheated copper turnings to remove O<sub>2<\/sub> respectively. The nitrogen obtained is not pure, it contains 1% by volume of rare gases and it is denser than air.<br \/>\nPure nitrogen is obtained in the laboratory by chemical method. The following chemicals are used to prepare nitrogen.<br \/>\n1.  Thermal decomposition of ammonium dioxonitrate (III)<br \/>\na. \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0NaNO<sub>2(aq)<\/sub>      +  NH<sub>4<\/sub>Cl<sub>(aq)     <\/sub>\u2192 NH<sub>4<\/sub>NO<sub>2(aq)<\/sub> +NaCl<sub>(aq)<\/sub><br \/>\n\tb.\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0NH<sub>4<\/sub>NO<sub>2(aq)<\/sub>     \u2192   2H<sub>2<\/sub>O<sub>(l)<\/sub>  + N<sub>2(g)<br \/>\n<\/sub><sub>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<img decoding=\"async\" src=\"https:\/\/ecolebooks.com\/nigeria\/wp-content\/uploads\/9jalessonsimages\/100423_1046_Week6SS2Se1.jpg\" alt=\"\"\/><br \/>\n\t\t<\/sub><br \/>\n\u00a02. \u00a0\u00a0\u00a0\u00a0Thermal decomposition of ammonium heptaoxodichromate (VI)<br \/>\n(NH<sub>4<\/sub>)<sub>2<\/sub>Cr<sub>2<\/sub>O<sub>7(s)<\/sub>     \u2192  Cr<sub>2<\/sub>O<sub>3(s)<\/sub>   +    4H<sub>2<\/sub>O<sub>(l)<\/sub>  +  N<sub>2(g)<\/sub><br \/>\n\t3. \u00a0\u00a0\u00a0\u00a0Oxidation of ammonia by hot Copper (II) oxide<br \/>\n\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a02NH<sub>3(g)<\/sub>     +   3CuO<sub>(s)<\/sub>      \u2192    3Cu<sub>(s)      <\/sub>+ 3H<sub>2<\/sub>O<sub>(g)<\/sub>  +  N<sub>2(g)<\/sub><\/p>\n<ol>\n<li>\n<div>Reduction of dinitrogen (I) oxide by red-hot copper.\n<\/div>\n<\/li>\n<\/ol>\n<p>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0N<sub>2<\/sub>O<sub>(g) <\/sub>      + Cu<sub>(s)<\/sub>        \u2192    CuO<sub>(s)<\/sub>         +      N<sub>2(g)<br \/>\n<\/sub><br \/>\n\u00a0<strong>INDUSTRIAL PREPARATION<br \/>\n<\/strong>Industrially, nitrogen is obtained by fractional distillation of liquid air.<\/p>\n<p>\u00a0<strong>EVALUATION<br \/>\n<\/strong><\/p>\n<ol>\n<li>\n<div>Write the electronic configuration of nitrogen and phosphorus.\n<\/div>\n<\/li>\n<li>\n<div>Using balanced equations, state TWO methods of preparing nitrogen in the laboratory.\n<\/div>\n<p>\u00a0<\/li>\n<\/ol>\n<p><strong>PHYSICAL PROPERTIES<br \/>\n<\/strong>1.\u00a0\u00a0\u00a0\u00a0It is colourless, odourless and tasteless<br \/>\n2.\u00a0\u00a0\u00a0\u00a0Pure nitrogen is lighter than air.<br \/>\n3.\u00a0\u00a0\u00a0\u00a0Slightly soluble in water<br \/>\n4.\u00a0\u00a0\u00a0\u00a0Melting point \u2013 210<sup>0<\/sup>C  and   boiling point is -196<sup>0<\/sup>C<\/p>\n<p>\u00a0<strong>CHEMICAL PROPERTIES<br \/>\n<\/strong>1. \u00a0\u00a0\u00a0\u00a0It reacts with very electropositive metals to form nitrides<br \/>\n\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a03Mg<sub>(s) <\/sub>    +       N<sub>2(g)<\/sub>    \u2192    Mg<sub>3<\/sub>N<sub>2(s)<\/sub><br \/>\n\t2. \u00a0\u00a0\u00a0\u00a0It reacts with non \u2013 metals like hydrogen and oxygen to form ammonia and oxides respectively.<br \/>\n\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0N<sub>2(g)<\/sub>     +       3H<sub>2(g)<\/sub>      \u2192   3NH<sub>3(g)<\/sub><br \/>\n\t\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0N<sub>2(g)<\/sub>     +       2O<sub>2(g)<\/sub>      \u2192   2N<sub>2<\/sub>O<sub>(g)<\/sub><\/p>\n<p>\u00a0<strong>USES<br \/>\n<\/strong>1. \u00a0\u00a0\u00a0\u00a0It is used industrially to manufacture ammonia.<br \/>\n2. \u00a0\u00a0\u00a0\u00a0Liquid nitrogen is used as a cooling agent.<br \/>\n3. \u00a0\u00a0\u00a0\u00a0It is used as preservative in packaged foods to prevent rancidity.<\/p>\n<p>\u00a0<strong>EVALUATION<br \/>\n<\/strong><\/p>\n<ol>\n<li>\n<div>State TWO physical properties and TWO chemical properties of nitrogen.\n<\/div>\n<\/li>\n<li>\n<div>Mention THREE uses of nitrogen.\n<\/div>\n<\/li>\n<\/ol>\n<p><img decoding=\"async\" src=\"https:\/\/ecolebooks.com\/nigeria\/wp-content\/uploads\/9jalessonsimages\/100423_1046_Week6SS2Se2.jpg\" alt=\"\"\/><br \/>\n\tThe stages in which atmospheric nitrogen is converted into soil nitrogen and back to free nitrogen occurs in the following ways:<\/p>\n<ol>\n<li>\n<div>Oxidation of atmospheric nitrogen: During lightning and thunderstorm, there is electrical discharge in the atmosphere which cause atmospheric nitrogen and oxygen combine to form oxides of nitrogen which can dissolve in rain water as dioxonitrate (III) and trioxonitrate (V) acids. These acids go into the soil and react with mineral salts in the soil to form trioxonitrate (V) salts which is absorbed by plants.\n<\/div>\n<p>N<sub>2(g)<\/sub>\u00a0\u00a0\u00a0\u00a0+  O<sub>2(g)<\/sub>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a02NO<sub>(g)<\/sub><br \/>\n\t\t\t2NO<sub>(g)<\/sub>  +  O<sub>2(g)<\/sub>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a02NO<sub>2(g)<\/sub>\n\t\t\t<\/li>\n<\/ol>\n<p>                4NO<sub>(g)<\/sub> + O<sub>2(g)<\/sub>   +  2H<sub>2<\/sub>O<sub>(l)<\/sub>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a04HNO<sub>2(aq)<\/sub><br \/>\n\t\u00a0\u00a0\u00a0\u00a0      4NO<sub>(g)<\/sub> + O<sub>2(g)<\/sub>   +  2H<sub>2<\/sub>O<sub>(l)<\/sub>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a04HNO<sub>3(aq)<\/sub><\/p>\n<ol>\n<li>\n<div>Action of nitrogen-fixing bacteria: Soil micro-organisms like Rhizobium living in root nodules of leguminous plants are able to convert atmospheric nitrogen into organic nitrogenous compounds which are used directly by the host plants. These compounds are released into the soil when these plants die. Other free living micro-organisms in the soil like Azotobacter and Clostridium are also able to convert atmospheric nitrogen directly into trioxonitrate (V) which is absorbed by plants. These processes are known as nitrogen fixation.\n<\/div>\n<\/li>\n<li>\n<div>Decay of organic matter: When plants and animal die, putrefying bacteria and fungi in the soil converts organic nitrogenous compounds to ammonia. Nitrifying bacteria like Nitrosomonas and Nitrobacter convert the ammonia to trioxonitrate (V) which can again be absorbed by plants. These processes are known as nitrification.\n<\/div>\n<\/li>\n<li>\n<div>Denitrification: Trioxonitrate (V) salt in the soil can be converted to gaseous nitrogen by denitrifying bacteria. The process is known as Denitrification. The nitrogen so formed escapes into the atmosphere, where it becomes atmospheric nitrogen. Denitrifying bacteria therefore reduces the quantity of trioxonitrate (V) in the soil.\n<\/div>\n<p>\u00a0<strong>GENERAL EVALUATION\/REVISION<br \/>\n<\/strong><\/li>\n<li>\n<div>Using balanced equation ONLY, show how nitrogen can be prepared in the laboratory.\n<\/div>\n<\/li>\n<li>\n<div>Outline the stages involved in the nitrogen cycle.\n<\/div>\n<\/li>\n<li>\n<div>Write the electronic configuration of N<sup>3-<\/sup> and P<sup>5-<\/sup>\n\t\t\t<\/div>\n<\/li>\n<li>\n<div>Balance the following redox equation: I<sup>&#8211;<\/sup>  +  MnO<sub>4<\/sub><sup>&#8211;<\/sup>  \u2192  IO<sub>3<\/sub><sup>&#8211;<\/sup>  +  MnO<sub>2<\/sub> in basic medium\n<\/div>\n<\/li>\n<li>\n<div>State the effect of the following on the equilibrium position of the reaction below: 3Fe(s)  +  4H<sub>2<\/sub>O<sub>(g)<\/sub>             Fe<sub>3<\/sub>O<sub>4(s)<\/sub>  +  4H<sub>2(g)<\/sub>  \u2206H = +ve\n<\/div>\n<ol>\n<li>\n<div>Increase in temperature\n<\/div>\n<\/li>\n<li>\n<div>Increase in pressure\n<\/div>\n<\/li>\n<li>\n<div>Using iron filings instead of iron rod.\n<\/div>\n<\/li>\n<\/ol>\n<\/li>\n<\/ol>\n<p>\u00a0<strong>READING ASSIGNMENT<br \/>\n<\/strong>New School Chemistry for Senior Secondary Schools by O. Y. Ababio (6<sup>th<\/sup> edition), pages 404-405, 422-423.<\/p>\n<p>\u00a0<strong>WEEKEND ASSIGNMENT<br \/>\n<\/strong><strong>SECTION A: <\/strong>Write the correct option ONLY<\/p>\n<ol>\n<li>\n<div> In which group of the periodic table is nitrogen found? (a) 2 (b) 5 (c) 7\n<\/div>\n<p>(d) 6\n<\/li>\n<li>\n<div>The boiling point of nitrogen in <sup>0<\/sup>C is (a) -183 (b) -196 (c) 200 (d) 240\n<\/div>\n<\/li>\n<li>\n<div>The percentage of nitrogen in air is (a) 78 (b) 75 (c) 71 (d) 67\n<\/div>\n<\/li>\n<li>\n<div>The following are uses of nitrogen except a. as a cooling agent b. to prevent rancidity c. in the manufacture of fertilizers d. in laundry.\n<\/div>\n<\/li>\n<li>\n<div>The atomicity of nitrogen is (a) 1(b) 2 (c) 3 (d) 4\n<\/div>\n<\/li>\n<\/ol>\n<p>\u00a0<strong>SECTION B<br \/>\n<\/strong><\/p>\n<ol>\n<li>\n<div>Briefly describe the preparation of nitrogen from air in the laboratory.\n<\/div>\n<\/li>\n<li>\n<div>State three physical properties and two chemical properties of nitrogen.\n<\/div>\n<p>\u00a0<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"<p>\u00a0WEEK SIX\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0DATE: _________ TOPIC:NITROGEN CONTENT General Properties of Nitrogen Family. Laboratory Preparation and Industrial Preparation&#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1,248],"tags":[],"class_list":["post-3075","post","type-post","status-publish","format-standard","hentry","category-posts","category-second-term-ss2-chemistry"],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/posts\/3075","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/comments?post=3075"}],"version-history":[{"count":1,"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/posts\/3075\/revisions"}],"predecessor-version":[{"id":3076,"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/posts\/3075\/revisions\/3076"}],"wp:attachment":[{"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/media?parent=3075"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/categories?post=3075"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ecolebooks.com\/nigeria\/wp-json\/wp\/v2\/tags?post=3075"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}