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GAS LAWS Questions

1.  (a) State Boyle’s law

(b) A column of air 5cm is trapped by mercury thread of 10cm as shown in the figure below.

If the tube is laid horizontally as shown in (b), calculate the new length of trapped air

(atmospheric pressure =75.0cmHg and density of mercury = 13600kgm-3)

 

(c) Explain why:

(i) It is difficult to remove the lid from a preserving jar which was closed when the

(ii) A force pump must be used instead of a lift pump to raise water from a deep well over 10m

2.  The figure below shows a simple set up for pressure law apparatus:-  

 

 

a) Describe how the apparatus may be used to verify pressure law  

b) The graph in the figure below shows the relationship between the pressure and temperature

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for a fixed mass of an ideal gas at constant volume

 

 

Image From EcoleBooks.com

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

  i) Given that the relationship between pressure, P and temperature, T in Kelvin is of the form

P = kT + C

Where k and C are constants, determine from the graph, values of k and C    

  ii) Why would it be possible for pressure of the gas to be reduced to zero in practice?  

 c) A gas is put into a container of fixed volume at a pressure of 2.1 x 105. Nm-2 and

temperature 27°C. The gas is then heated to a temperature of 327°C. Determine the

new pressure  

 

3.  (a) State Boyle’s law  

 (b) The volume of a bubble at the base of a container of water is 3cm3. The depth of water

  is 30cm. The bubble rises up the column until the surface

(i) Explain what happens to the bubble as it rises up the water column

(ii) Determine the volume of the bubble at a point 5cm below the water surface

 (c) A faulty thermometer records 11oC instead of 0oC and 98oC instead of 100oC. Determine

the reading on the thermometer when dipped in liquid at a temperature of 56oC  

 

4.  (a) State Boyles law

  Some students carried out an experiment to verify Boyle’s law and recorded their results as

shown in the table below:-

Pressure KN/ M2

400

320

160

180

Volume (m3)

2.0

2.5

5.0

10.0

1/V (mm-3)

    

(i) Complete the table

(ii) Plot a graph of pressure against 1/volume

 (c) Determine the gradient for the graph and state its units  

(d) A sample of gas has a pressure of 1.0 x 105Pa when its temperature is 10oC. What

will be its pressure if its temperature is raised to 100oC and its volume doubled


5.  (a) State: (i) Boyle’s Law  

(ii) Charles’ Law.

(b) A form three student carried out an experiment on one of the gas law. She obtained the

following results.

Temperature (0c)

10

35

60

80

90

110

Volume V(cm3)

5

5.8

6.4

7.0

7.2

7.8

(i) Plot a graph of volume V against temperature.

(ii) From the graph, determine the volume of the gas at 0oc.  

(iii) Determine the slope of the graph.  

(iv) The equation of the line obtained is of the form V = kT + c. What is the value of k and c?

 

6.  (a) State Charles’ law

 (b) A mass of gas occupies a volume of 150cm3 at a temperature of -73°C and a pressure of

1 atmosphere. Determine the 1.5 atmospheres and the temperature 227 °C

 

7.  In an experiment to verity Boyle’s law, two quantities were advised to be kept constant

 (a). State the quantities.

 (b). the results of experiment to verify Boyle’s law were recorded in the table below.

Pressure(atmospheres)

1.0

1.2

1.4

1.6

1.8

Volume (litres)

0.62

0.521

0.450

0.391

0.351

 Plot a suitable graph to verify the law.  

 (c). Determine the volume of the gas when the pressure is two atmospheres.

 

GAS LAWS Answers

1.   (a)  It states that the pressure of a fixed mass of gas is inversely proportional to its volume

provided temperature is kept constant  (PV = K)

 (b)  P1L1 = P2L2

86 x 5 = 75 x L2

  = 5.73cm

 

(c) (i) When steam condenses, the pressure inside the container will be lower than the

atmospheric pressure on the outside. The excess atmospheric pressure acting on the lid

exerts a force on the lid thus making it difficult to open the lid.

(ii) The lift pump depends only on atmospheric pressure which can only support a column

of water 10m long. The force pump uses force and therefore can lift water to the length

greater than 10m.

 

2.  a) Describe how the apparatus may be used to verify pressure law  

Plotting pressure against absolute temp we get a straight line graph

 

Conclusion

Pressure of infixed mass of a gas indirectly proportional to its absolute to temperature if volume is kept constant  

 

b) i) Given that the relationship between pressure, P and temperature, T in Kelvin is of the form

P = kT + C

Where k and C are constants, determine from the graph, values of k and C

K = gradient  

 = (8-0) X 104 NM -2  

  200 – 0

  K = 400N m-2 K-1

  C = O  

ii) Why would it be possible for pressure of the gas to be reduced to zero in practice?  

  • The gas liquefies at low temperature before reaching zero Kelvin

c) A gas is put into a container of fixed volume at a constant volume at a pressure of 2.1 x 105.

Nm-2 and temperature 27°C. The gas is then heated to a temperature of 327°C. Determine

the new pressure  

 

 

P1 = P2  T2 =273 + 327  

T1 T2 = 600K

P1 = 2.1 X 105 Nm-2 P2 = P1 T2

P2 = ? T1 2

T1= 27+ 273 = (2.1 X 600) X 105NM -2 = 4.2 X105NM-2  

= 300K 300

3.  a) The volume of a fixed mass of gas is inversely proportional to its pressure provided

temperature is kept constant.

(b)   (i) The bubble expands as it comes up finally bursts when at the surface

(ii) p1V1 = P2V2

(76 + 30) x 3 = (76 + 5) V2

106 x3 = 81 X V2

V2 = 106 x 3

81

= 3.93cm3

 

(c) 100oC – 0oC = 98 -11

1 division = 87

100

Reading = 8 x 56

1000

= 48.72oC

 

4.  a) The volume of a fixed mass of a gas is inversely proportional to the pressure provided

that temperature is kept constant  1

 

1/v (mm-3)

0.5

0.4

0.2

0.1

 

 b) Labeling the axes

  Scale

  Plotting (3,4) pts

  2 points  

  Below 2 points  

  Smooth curve / straight line

 

 c) Gradient = Δy

Δ x

= 400 – 160

(0.5 – 0.2) X 10-9

 1

= 340

0.3 X 10-9

= 1133.33 X 10-9

= 1.1333 X 10-6 KNM

 

 d) P1V1 = P2V2

  T1 T2
 1

1 X 105 X V1 = P22V1  1

285 373

P2 = 6.95 X 104 Pa  1

 

5.  a) Boyles Law: States:-

 (i) – The pressure of a fixed mass of a gas is inversely proportional to its volume, provided the temperature is kept constant. 1

 (ii) Charles Law states:

– The volume of a fixed mass of a gas is directly proportional to its absolute temperature at constant pressure. 1

 

 b) (i)

 (ii) at 00c, v = 4.7 cm3
+ 0.1 1

 (iii) Slope = DV

DT

= (6.4. – 50)cm3
1= 0.028 cm3/0c + 0.002 1

    (60 – 10)0c

 (iv)  V = KT + C.

 K = Slope = 0.028cm3/0c + 0.002 1

C = V intercept when T = 0 and 1

= 4.7. cm3
+ 0.1

 

 

 


 




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